Causes of Bubbles and Voids
A. Dispensing Issues The method of applying the adhesive is the most frequent source of air entrapment. High Dispensing Pressure or Speed: Too much pressure or too fast a dispensing rate can inject air directly into the adhesive or cause turbulence, trapping air within the fluid stream. Improper Nozzle Design: If the dispensing tip is too narrow or the syringe/reservoir contains headspace, air can be incorporated during application. "Tailing" or Lifting the Dispenser: Pulling the dispensing needle away from the adhesive too quickly can create a vacuum that pulls air into the material. B. Substrate Issues Air can be introduced from the components being bonded. Porous or Rough Substrates: Materials like ceramics, composites, or lightly-abraded plastics may have microscopic pockets or surface roughness that trap air, which is then released into the adhesive when the substrates are mated. Mating Technique (Air Vents): When two flat substrates are brought together, air can be trapped in the center. C. Chemical Reaction (Outgassing) In rare cases, the adhesive itself can generate gas. UV Intensity Spike: If the UV light intensity is too high, the polymerization reaction becomes extremely rapid and exothermic (heat-generating). This rapid chemical change can cause volatile components or gasses to "outgas" within the adhesive, forming bubbles. 2. Solutions for Eliminating Voids A. Pre-Process (Adhesive Handling) Degassing: Use a vacuum chamber to degas the adhesive in the syringe or reservoir before dispensing. This removes any air dissolved or trapped within the liquid adhesive, especially for large-volume applications. Allow Equilibration: If the adhesive has been refrigerated, allow it to reach room temperature before use. Cold adhesive is thicker (higher viscosity) and holds air more easily. B. Dispensing and Mating Techniques Lower Dispense Rate and Pressure: Reduce the dispensing pressure and speed to ensure a smooth, laminar flow of adhesive without creating turbulence. Dispense Pattern: Use a dispensing pattern that ensures the adhesive is applied to one substrate only (not both), allowing it to wet out properly when the parts are mated. Controlled Mating (Air Vents): Bring the substrates together slowly, starting from one edge and applying a uniform closing pressure. This method, like closing a book, forces the air to escape out of the sides rather than trapping it in the center. Increase Dwell Time: After dispensing and before curing, allow a short dwell time (a few seconds) for the adhesive to settle and for any small entrapped air bubbles to rise to the surface and burst. C. Curing Optimization Ramp Curing: Use a step-cure or ramped intensity curing profile. Start with a very low UV intensity and gradually increase it. This slower cure rate prevents the rapid heat spike and outgassing that causes bubbles. Vacuum Curing: For high-reliability, void-free bonds in optics or medical devices, cure the adhesive while the assembly is temporarily held under a vacuum. This pulls any remaining dissolved or trapped air out of the liquid adhesive.