Choosing an Adhesive for Thermoplastics: Compatibility, Stress, and Environment
An adhesive that passes a bench pull test can still fail in the field within months. The gap between the two is almost always chemical compatibility, locked-in stress, or an environment the bench never simulated. A durable thermoplastic bond accounts for all three before production starts. Substrate Compatibility Compatibility runs two directions. The adhesive has to wet and grip the plastic, and it must not attack it. Polycarbonate and some rigid PVC formulations are prone to stress cracking when exposed to aggressive solvent-based adhesives or to the solvents in some primers. An adhesive that bonds strongly but crazes the substrate has traded one failure mode for another. Verify compatibility by bonding stressed coupons, bending a bonded strip over a mandrel, holding it under load, and inspecting for surface crazing after 24 to 72 hours. Light-curable acrylics and well-chosen cyanoacrylates generally avoid this problem on sensitive resins, but confirm it on your specific grade. Cure Shrinkage and Locked-In Stress Every adhesive that cures by polymerization shrinks as it does so. If the bond is rigid and the shrinkage is high, the interface carries that stress before the assembly sees any external load. Over time, combined with service stress, it drives delamination. Two levers reduce the problem. Choose a grade with low linear shrinkage, and keep the bondline thin so the absolute shrinkage displacement stays small. For joints between materials with different stiffness or expansion rates, the mechanism is the same one described in how CTE mismatch causes adhesive bond failure, and a slightly flexible adhesive relieves it. Environmental Resistance Match the adhesive to the real service conditions: Humidity. Absorbed water plasticizes many adhesive polymers and lowers shear strength. Specify low water absorption for outdoor or washdown service and confirm with damp-heat aging at 85 percent relative humidity. Temperature cycling. Repeated expansion and contraction fatigues the interface. Run at least 100 cycles across the full service range on sample parts. Chemical exposure. Fuels, oils, cleaning agents, and disinfectant sprays can swell or attack both adhesive and substrate. Test with the actual chemicals, at the actual concentration and dwell time. For help mapping your service environment to an adhesive spec, Email Us. Viscosity and Application Compatibility and durability mean nothing if the adhesive cannot be applied cleanly. Low-viscosity grades wick into tight pre-assembled joints; thixotropic grades hold position on vertical or overhead surfaces. The Uni-Weld plastic bonder line is arranged by viscosity and substrate so the working properties are part of the selection rather than an afterthought. Cure Method Light-curable adhesives cure in seconds where a lamp can reach, which favors clear parts and open joints. Delivered dose determines cure quality, so verify irradiance at the part with a radiometer and account for lamp aging. For a primer on choosing a light source, see selecting a UV lamp for resin curing. Two-part systems cure regardless of light path but require fixturing through the cure. Surface Energy and Wetting An adhesive grips a plastic only if it can wet the surface, and it wets…